CAS to Membrane Aerated Biofilm Reactors: Scope, Applications, and Challenges - Prof. C. Visvanathan
eXRWkaHKTgg • 2020-08-11
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Kind: captions Language: en session i also want to greet all of you who are currently watching this webinar via youtube live stream and i hope you can enjoy this webinar session and can get a lot of new insight before we start it is highly recommended that you subscribe to the psl interview channel and click on the bell next to it so you don't miss out any information about our other webinars even in the previous discussion we discussed a lot about this characteristic of wastewater the principle of selecting technology and planning for wastewater facilities now we will discuss of one of the specific wastewater treatment technologies we call it aerobic biological treatment processes more specifically we will discuss in sufficient details about one of biological wastewater mechanics namely membrane aerated biofilm reactors or we usually call it mbr generally if we talk about aerobic treatment we know a lot about and even designing our wastewater treatment facilities using activator slides right but to use it active and slots require an additional unit namely the clarifier or etc to separate the solid however what if we can get both of this functionality in just one unit to find out more about these things we will discuss it furthermore in this session which we titled conventional activator sludge to membrane edited by a film directors scope application and challenges without wait any longer we will be thought by a professor from the asian institute of technology who has published more than 150 international journal papers more than 20 years of experiences teaching environmental engineering and management related courses at graduate level at ashen institute of technology he also has interest in researching on membrane technologies for water and wastewater treatment by focusing on development mbr systems water recycling and industrial waste water treatment and also cleaner production and salt waste disposal and management so immediately with all the following experience we hope to get interesting scientific knowledge and discussion with all of us in this discussion and in this session with professor fish fanathan and prof you may start your session right okay now you yeah bye okay thank you very much good morning chandra and good morning okay i'm bishop let me take the next 50 minutes to give a short presentation on conventional activate slides to membrane aerated bioflame reactors thanks a lot for the nice and very crispy introduction let me move into my slides okay you can see my slides uh yes good morning i'm going to talk to you about conventional activate sludge to membrane aerated biofilm reactors i think most of you know what is conventional activate sludge and most of you know what is membrane bioreactors so i'm going to talk to you the bridging gap between these two how membrane bioreactors move to the next level what we call membrane aerated biofilm reactors okay if you look at the current scenario okay huge amount of domestic wastewater is produced okay it's come from household industries agriculture hospital and recreational activities etc etc wastewater treatment has become essential for removal of pollutants okay we need to remove them before we discharge into waterways to a large extent in the past we focus on removing organics that is what a conventional activate sludge process will do it will remove the organics but still leaves the nutrients or the nitrogen and phosphate in the water so we discharge waste water removing organics but still containing nitrate and phosphate that creates the sufficient amount of environmental degradation but because of that in the last 10 years national governments of emphasize in asia pacific region to remove these nutrients so the wastewater treatment plants need to be changed or need to be modified to remove nitrate and phosphate i think this you know very classic typical acute sludge process preliminary treatment primary sedimentation aeration tank sedimentation then you have depending on the discharge point you need chlorinate and discharge and you can see to a large extent in this process we will have suspended growth of microorganism so the organics gets trapped in between okay it could be physically trapped or biochemically convert into carbon dioxide and water by microorganisms and the growth and this microorganisms are removed as slides and you get the treated water so in this process uh the microorganisms to survive we need to use huge amount of electricity okay and you need to supply air only a small percentage less than 30 percent of the air v supply it's consumed by these microorganisms so there's a huge inefficiency how we provide air inactivates that process okay and it's also very important on this process it's basically the organic is removed the nitrate and phosphate is removed only a small fraction it is converted by microorganisms to growth but otherwise a huge amount of nitrate and phosphate remains and this last you will see travel around the region you will find huge wastewater treatment plants like you can see that aeration tank sedimentation tanks in china or u.s and this is what you will find a huge activate slice treatment plant works very well okay but doesn't remove all pollutants but mainly removes the organic pollutants and it's also a huge cost of operational cost in terms of power consumption to overcome this problem and the last 10 15 years we are moving into a membrane bioreactor i will not explain that too much but the membrane bioreactor essentially consists of if you look at it you have an aeration type and you have a sedimentation tank you can see the amount of surface area in use we could bring them to a smaller area and that is done by combining both of them together so you can see bring that aeration and the sedimentation in one tank in some sedimentation we can put a membrane okay and that could be a compact system and a better quality which called membrane bioreactors okay still if you look at it here uh if you look at it here in this one settling of biomass is not a problem okay unlike in a conventional activity process that's becomes a very attractive and you get an excellent quality water very often we could reuse it and these are the advantages of membrane system membrane bioreactors and you can see a typical membrane bioreactor system and you can see it has a small footprint doesn't have a smell order problem you don't need too many workers because you can automate the whole system amount of sludge produces less and also the system is has a higher biomass and robusting and it can take into a shock loading much better than conventional electrical process and it's very attractive selling point of this technologies is we have a very high quality effort and the effluent is without suspended solids without organics reduce nitrogen so this water treated water could be reutilized so it's become more and more attractive to use these membrane bioreactors and the membrane bioreactors can come into three typical configuration you can have an aeration tank and put the membrane outside which called external membrane or you can put the membrane directly into an aeration tank this is we call the second generation membrane bioreactor which becomes a relatively not popular these days what we want today is we keep this membrane outside the thing which is called membrane airlift system okay or sometime we call side stream membranes so the main biological process takes place here the membrane is kept outside the systems this is becoming more and more popular okay if you look at on this one activate such process and a membrane bioreactor and of course membrane bioreactors in all terms very attractive all the disadvantage of our activates with process can be overcome by memory but only issue there is is for membrane bioreactor system to avoid or to eliminate the bio falling or deposition of solids on the membrane surface what we do is is we need to aerate huge amount of we need to send huge amount of air bubbles something called surface scrubbing and that leads to very high energy consumption and that is one of the main issue make membrane bias unattractive it is energy consumption it is not the membrane performance and what it used to be 10 years ago okay so now to overcome this energy thing what we are moving today is is membrane aerated biphobia and in a membrane bioreactor we use a membrane to remove the biomass so get a very high quality water but membrane aerated biofilm reactor we do it differently we use the membrane not for filtration but we wanted to provide oxygen through the membrane so membrane function is not for filtration it is used for diffusion and the idea is is as i said in these two process only 30 of oxygen we use actually utilize so that means 70 percent has become wasted whereas in this if you're diffusing you could achieve as significantly closer to 92 percent of the oxygen can be or air can be utilized for biodegradation process so that is what's the attractiveness okay that's what we call membrane aerated bird let me brief you a little bit more on the technology okay here you can see a membrane okay specimen okay in which air is allowed so the air is passing through the oxygen this diffuses through the system and surrounded by the membrane fiber the biofilm will grow both at this concentration here there's a huge amount of oxygen so you can have a nitrophiles and as it goes down the air diffuses through the thing the oxygen concentration reduces then you could have two different microorganisms growing nitrifiers and denitrifies because one is a higher oxygen concentration low concentration so you can use this one you can see you could achieve around 80 plus on the saving energy cost using this one maximum so bioflame is grown on the membrane surface okay more the biofilm grows more the pollutants get degraded okay so we are moving away from bubble aeration which is used in membrane bioreactor to diffuse variation so air is diffuses through the membrane so if you look at how it look like in a systematic way you have a raw sewage or all wastewater do a pre-treatment exactly like membrane bioreactors like okay maybe a micro screen primary sedimentation etcetera and do a pre-treatment depending on the thing then you put into a reactor okay so now the reactor in which you can see air is diffused through the membrane so air is never sent as a bubble so as is diffuse through almost all the oxygen is consumed and that is the strength of the system so now the biomass will grow here both nitrification denatrification organic removal takes simultaneously and the biomass is taken out and goes into a next at clarifiers time okay has small sedimentation time okay the biomass is removed and treated waters taken out and this waste water meets both organic and the nutrient removal requirements this is a sort of a conceptual system now the supplied air could be a air or in some cases it could be a pure oxygen okay that could be anything but at the moment we are working only on the air as a industrial application if you look at a working principle okay so you can see the oxygen okay supply through the membrane and it diffuses through the membrane so it's more important the membrane should allow the air to diffuse through the system okay it's very important okay normally a hydrophobic membrane okay supply of oxygen through the lumen of membrane oxygen diffuses through the membrane surface okay and now as it diffuses oxygen concentration at the surface of the membrane it's very high so you will have okay aerobic condition which promotes an autotrophic bacteria which are the nitrification okay and the organics are removed here and as it goes down the oxygen concentration comes to small close to zero then the denitrification and oxygen condition is taking place okay so from conversion of ammonia to nitrite right okay so here you can see a membrane we call self-respect membrane to achieve the aeration depending on the conditions for moth nitrification and denitrification can takes place these are the classic environmental engineering equations i think i'm not going to these i presume the previous presentation process chandra pointed out this so i think these are very classic but what i want to say is two conditions one is nitrification and denitrification one we need high amount of oxygen one you need a very low amount of oxygen so these two conditions can be achieved one system okay and it's also is very interesting simultaneous nitrification and denatification can take place on membrane aerated bioreactors you can see the theoretical concepts began on this one the eliminates the need to use two separate tank normally if you know that conventional activates such process if you wanted to remove nitrogen and you have an anoxic tank from the front and etcetera and it's also very important in such situation the ph need to be maintained and here you can see when you do it both at the same time it becomes very interesting the alkalinity consumed in the nitrification is produced by the denatrification process that means there's a less demand necessity for alkalinity okay so you can see an mabr technology is a disruptive to a conventional wastewater treatment system so we see the future of the wastewater treatment plants especially in a decentralized system maybe become very very attractive during the next few years and you will see more and more attractive research what has been done now to look at it here this is a cross-section of membrane lumen and oxygen diffuses from inside to outside and the pollutants moves from bulk liquid towards the membrane surface and it gets degraded and it's very important here in this one the bioflame layer should grow okay the whole process depends on the biofilm layer growth and the thickness of the biofilm growth we don't want the bioframe layer to be very small then you will not have a nitrification identification and we don't want the biofilm to too thick then in the end of the process you will not have sufficient uh okay had to be come for denitrification process okay so we need to come into this very carefully okay the major functions here supplying oxygen which supports the biomass growth and the membrane material as the air has to pass through it has to be hydrophobic and you could have a different type so i've come into that in the next slide slide the configuration could be a honor fiber a flat sheet or tubular but today in a commercial activities it is only holder fiber and tubular becomes attractive and the design parameters unlike in membrane body like this the membrane thickness and the specific membrane surface areas plays a very important role let me take you to three minutes a small video clip please look at this one then i'll come back to the next discussion urban infrastructure bacteria need oxygen to break down wastewater over the past hundred years oxygen was delivered by bubbles a very energy intensive process with bubbles rising quickly bacteria struggle to get oxygen with 70 wasted oxymen changes that why no bubbles that's so old-school our oxygen is still a bit direct no hassle with oxymoron bacteria grow on gas permeable membranes for the direct supply of oxygen thousands of membranes are held in cassettes like this enabling more effective bacterial growth on each membrane wall meaning bacteria work more efficiently without oxygen bubbles the cassettes are inserted into an oxymet cage which can be part of a package plant or retrofitted into an existing tank okay that tells you a typical maybe a process how it looks like on a video okay now let me take the next part how these mabr membranes in terms of engineering configuration the first one we call dead end configuration so the membranes are placed here the air supplies comes here the bottom part it's closed that's means we call it a dead end i oxygen transfer efficiency okay but it's also is very important uh in the later part okay as oxygen passes through the nitrogen can back diffuse into the system so it's not that attractive the first generation mabr people worked on this one but today we prefer because to have a cross flow configuration whereas outlet okay the carbon dioxide the gas outlet and the nitrogen will be removed here which avoid the back diffusion but of course when you talk about oxygen transfer this might be less efficient compared to the dead end okay so but still from a practical point of view today to a large extent we prefer to use a cross flow configuration okay so keep that in your mind and mabr we do not like to use the dead end configuration okay in a practical applications i would like to share this information with you okay now if you look at it a little bit more engineering point of view okay uh how the bio frame will look like this okay so if you have a conventional contribution okay and here you can see this one normally oxygen okay you have an attachment surface okay so aerobics oxygen is here so aerobic is on this side and the nitrifiers is on this side it's a very classic conventional coefficient okay both aerobic and neutron rich so exists at the biofilm surface okay you can see this one this one but if you look at it in mabr one the oxygen is coming from this okay so the nitrifier concentration is on this one okay that is where the oxygen is necessary and you can see on this the oxygen concentration produces here okay and then you can see this is aerobic electrophiles are here okay so low cod and high deo concentration near the bio frame attachment surface favors the growth of nitrifying bacterias and whereas on this part favors the need the nitrifying condition so you can see you could create in a biofilm unlike in this case both nitrifying and denitrifying conditions it's very interesting so that can be put into another way or we can see this one so membrane surface this is a waste water so you can see here lumen and the membrane surface and the waste water so oxygen concentration is very high here and when it comes to here the biofilm okay this is waste water it's almost become zero so you can see different parameters so cod concentration is very high here and with the cod concentration at this point becomes almost zero okay so you can see this in aerobic autotrophs aerobic ectodrops and anoxic heterotrophs you can see this one what happens in this system this is what happens okay in a memory aerated biofilm reactor and that could be put it onto this angle so you can see the oxygen is keeps moving the biofilm grows the b o d is pushed from the bulk liquid as it goes within and the nitrate comes out here the nitrogen okay you can see this one very clearly how the biofilm growth is taking place okay which can be used again okay so here you can see this is what we call membrane and the biofilm and what is important is how do you maintain the thickness of this biofilm we don't want the biofilm thickness to be too big or too small as expected okay and as with the time like a trickling filter the biofilm need to be removed continuously okay and we need to create the condition so that biofilm could be removed as some detachment of particles or sludge which could be carried to the next unit operation of sedimentation biofilm thickness due to particle attachment and detachment depends on substrate availability and the mixing condition the reactor so this is the most interesting the engineering part of the membrane aerated bioreactor design let me move into that next part in terms of membrane today to do this aeration there are three different types of membranes i use one is micro porous membrane okay so unlike it's like a micro filtration air is passing through the pore and the pores size should be as small as possible so that the air is allowed to pass through this one as a bubble okay the second one is a dense membrane like a silicon membrane okay there is no pore but air is allowed to diffuse through the membrane okay it's very interesting which called a dense membrane uh we are working on this type of membrane earlier we also do a lot of work okay the oxymerm is one company which is manufactures a very interesting and dense membrane but there is also possible today both diffusion uh sorry microporous and the dense membrane can be combined together which is called composite membrane so more and more the new membrane manufacturers who are moving from membrane to be used as a filtration that used to be a big marker it will continue as a big market but if you look at what the future market of membrane technologies using membrane as a diffusion process like this type of thing where people are working on a diffusion a composite type of membrane okay in terms of configuration only two types are very attractive what is the tubular one okay you can use this one also spiral wood it's exactly like ro memory okay let me take you to one more video clip how the spiral would membrane works in a membrane aerated bioreactor biological treatment in an msc mabr plant is made up of multiple mabr modules such as this one shown inside a module tank there is a spirally wound membrane sleeve with spacers as an airflow spacer separates between the walls of the membrane sleeve a water spacer separates between wraps of the sleeve oxygen from the air diffuses through the membrane into the water side where there is dissolved ammonium as a result a nitrifying biofilm develops on the surfaces of the membrane nitrate is generated as a product of the nitrification process and discharged back to the water these conditions are enabled by the presence of a high concentration of biomass suspended in the water body the suspension known as mixed liquor tends to settle within the water body periodic release of air from the bottom mixes the entire water volume and homogenizes the mixed liquor mixing flow follows a pattern of an air lift rising through the spiral spacings and flowing downwards through the core short mixing durations a few times per hour are sufficient to sustain the mixed liquor the suspended solids for the process are provided by a secondary clarifier like in the activate sludge process mixed liquor is fed to the clarifier where it is separated by gravity into two streams a concentrated sludge at the bottom and a clarified effluent at the top the sludge is circulated back to the process and the clarified effluent is discharged for direct reuse or further processing the biology okay that one presents very clearly how spiral wound membrane works in an mabr reactor and a commercial one so that gives you an idea of what's happening in the field now let me tell you something about factors influencing mabr treating both organic and total nitrogens okay one is membrane packing density it's important and oxygen supply rate dissolved oxygen ph and it's very important ph and alkalinity because we are looking at simultaneous nitrification death nitrification and hydronic retention time and it's also very important we should have hydraulic retention time as small as possible okay organic loading weight okay and very important for to have simultaneous magnification and denaturation the ratio of cod to nitrogen ratio should be somewhere around five okay and thickness of bioflex these are the influencing parameters those of you are interested in conducting research or looking at a research direction i just summarized these are the factors you might have to look into that for developing and working on maybe let me take the next 10 minutes summarize some of the application and what level of this technology may be technology today is still in between the pilot to the industrial scale okay there are few industrial scales but it is not as strong as membrane bioreactors today membrane bioreactor is is for domestic wastewater it is a proven technology the amount of research you can do which is very marginal but if you look at mbbr there are a lot of potential okay for young researchers like what you can see the type of research work has been done i just summarized okay it is used for landfill leaching pharmaceutical industries ammonia rich synthetic wastewater domestic wastewater and it's quite interesting it's not only worked on the domestic one it's also can be used xenobiotic or very what do i call um extremely uh polluting organic pollutants okay um let's say for example acetate two lawn and all these components uh organic pollutant which can biodegrade easily by aerobic process the problem is is we cannot use and activate such process because these are very volatile compound okay so when you use an air an activation process a significant part of them will strip out as a air pollutant so all the aerobic process can be utilized conventional membrane bioreactor process cannot be used because of this walletization issues whereas these things let's say for example we worked extensively a component called acetonitrile okay it's a strong organic pollutant highly volatilized and easily biodegradable in the aerobic process but we cannot use conventional process because the air could strip them out so what we do is we use membrane aerated bioreactors so where membranes diffuse through the system so there is no volatilization and the complete degradation can take place so this is one interesting domain so where membrane aerated bioreactors can be utilized so specifically for industrial pollutions containing volatile organic compound which can easily biodegrade okay in aerobic process you can look at this one okay treat a deaf rule okay uh the difference okay you can see inlet you can see an outlet and it is very important the outlet of the membrane it's not crystal clear like membrane bioreactor in membrane direct sometimes the treated effluent is better than the drinking water in terms of turbidity some some situation because it's a membrane filtration but here please understand it is not filtration it is an effluent from a sedimentation okay so if you wanted to reuse it okay and you need to think of what type of application you can use it's important okay so like here you can see some of these applications are pointed out right treatment of high loading pharmaceutical waste water and as i told you here many of the pharmaceutical compounds will have toxic organic chemicals and which are easily biodegradable you know aerobic conditions and you can see this one can be utilized okay high cod and nitrogen removal rates can be obtained membrane aerated bioreactors okay so here you can use simple pvdf membrane okay and you can see that there are other application reduction of nitrate and perchlorate from groundwater and some situations okay when you want to remove this one okay it's easy to use okay membrane aerated bioreactors i will not go into the details but if you are interested you can read these documents you can see that how and what domain is being utilized but when it comes to today commercially there are two leading companies okay zen and zebido ge as this general electric has bought this company called zeelong and this is one of the commercially available membrane aerated bioreactor company okay another one is oxymet okay this uses a porous membrane this uses sort of a dense membrane okay and i like to tell you there are many new membrane developers are working on this domain and we ourself are working with some companies because many membrane manufacturers look this domain as an interesting future growth potential of membrane okay so the next five to ten years you will find a huge number of membrane new domains to use not membrane bioreactors but to work as a membrane aerated bioreactor systems okay and the industrial applications okay let's say there's a company called fluence the first mainland u.s membrane aerated pilot pile pilot plug in which is uh used okay which is to meet the california's stringent uh nitrogen removal standards okay with a capacity of 11 meter cube per day so it's more of a pilot scale so you can see this one so you can see the membrane aerated bioreactors have been neutralized since in brazil okay it has been in spain still somewhere between to pilot scale to a industrial scale not a big scale okay a semi pilot or semi industrial scale i would say this one okay there are a lot of more and more industrial scale applications have been taking place in different parts it's become very popular the fluence membrane technology was originally developed in israel so it's quite popular in israel okay to use this technology so there are a variety of applications you can see this one where that's uh this type of system can be utilized in package systems simple systems exactly like membrane bioreactors you can download this one and you can package it it's becoming more and more popular so here you can see this one this is really comforting influence it says yes okay i'm in a meeting can i call you okay uh sorry for the call so you can see this one okay now let me take the next 10 minutes what type of research we are doing at ait okay that tells you what are the research potential okay and what type of work and this tells you we wanted to by download for increase the removal efficiency of organics and the total nitrogen the bench scale membrane the issue we addresses is normally we can achieve organic removal very high in conventional mbr systems but the problem is is when you wanted to remove the nitrogen it becomes a difficulty so that is why we wanted to use membrane aerated bioreactors okay and we also want to do this one as a short hrt as possible okay so here we can develop a membrane dense membrane it's a oxymoron a reactive okay and the waste water is added onto the theme and we could achieve a certain amount of nitrogen so we could not achieve the full denitrification process for that we what we did is we created added in this reactor a type of gel pv agent where the denitrified microorganisms are captured and grown so the wastewater is introduced on this organic and nitrification takes place here and the denitrification takes place here part of the denotification on the biofuel the risk taking place here this experiment set up so i'll show you this video so to tell you some snapshots hello everyone my research topic is enhancement of organic matter and total nitrogen removal in maybe are using bile carriers and these are the objectives of my research as you can see in this video there are two reactors with two different configurations and now i will explain you about their operation first i will explain you the operation of the reactor on my right side as you can see it has three compartments which are hydraulically connected and the compartments on either side contain the membranes here are the characteristics of these membranes as you can see here the biofilm has already grown on the membrane surface in the middle compartment there is pva gel it is a type of bile carrier and i have already grown denitrifying bacteria on them and these are the characteristics of these bile carriers and this is how i grew bacteria on them in addition i have provided good mixing in the middle compartment using a mechanical mixer so the whole purpose of this modification is to improve denitrification now let's see how this works first synthetic waste water with the required cod to end ratio is prepared and stored in this storage tank then using this peristaltic pump it is pumped into the reactor with the required flow rate using pu tubes waste water enter the reactor through the valves on either side of the reactor as waste water enter the reactor first to get treated by the biofilm on the membrane surface thereby nitrification and denitrification take place by this uniquely stratified biofilm after that the waste water enter the middle compartment through the perforated walls thereby further denitrification takes place by the biomass inside pva gel after getting treated like this the treated water is collected in the bottom of the middle compartment as you can see there is a very small diameter glass tube attached to the wall of the middle compartment water is taken to the top through that tube and through this pu tube it is taken to a settling tank after settling down the heavy particles the treated water is collected in a separate collecting tank like this and now i will explain the operation of the other reactor which has a different configuration this reactor contains a different membrane and these are the characteristics of the membrane this reactor has a cylindrical shape so the procedure in here is also the same as the previous waste water is prepared and stored in this storage tank and it is pumped into the reactor using this peristaltic pump here also waste water enter from the bottom of the reactor and get treated by the biofilm on the membrane surface then the treated water is taken out from the top after that it is taken to a settling tank and after settling down the heavy particles the final effluent is stored in a separate tank now let's see the results of these two experiments here are the results of objective one of the research here i have calculated the required operating pressure at each hrt using the otr experiment results which have been carried out previously now let's see the results of objective two here is the cod removal performance and here is the total nitrogen removal performance of the two reactors at different hrts and cod to n ratios thank you hello everyone my wrist okay that video clips tells the type of the research we have conducted in iit okay and this research resulted in a publication okay and you can see it was published in the bio resources technology report and this is one of the work on this one in parallel to this we also did another research okay studying on the mabr performance on a xenobiotic compound and as i told you earlier we looked at certain xenobiotic compounds because which can volatilize normally but it can be biodegradable aerobically so that we cannot use an accurate such process so we use the diffusion system may be a systems and we can date the similar type we can see the reactor the waste water is exactly passes through this reactor you have this membrane dense membrane which is used for aeration okay the aerobic degradation takes place through the biomass okay and we can see this one and we the effluent comes out here and the effluent performance and etcetera admission and which is again published this is american society of civil uh uh civil engineering american journal of environmental engineering or american society of civil engineering it is published okay you can look at this information okay just to tell you type of the work so from this laboratory work doing fundamental research currently we are moving into this to develop a pilot scale experimental work which talk about mabr to treat actual domestic wastewater within our campus okay we are going to the next scale uh we are working with some actually developing and how nitrate and phosphate could be removed and the focus for us is most importantly developing a very compact and fully automated system so we have developing systems within the campus so that the we could monitor them okay from a distance so the idea is is to promoting decentralized wastewater treatment systems using this type of system okay let me move into the next part i would like to tell you that what are the interesting research developments taking place i talked about the conventional one now i want to tell you what is the research development because if anybody like to work on mabr which direction you should look into that some of the research direction themes involved in this the first one is people are working on two stage startups instead of having a one single stage nitrification and denatrification taking place it's also possible sometime much easier you could break this into two components a nitrification on one side okay and the d notification is a second stage okay because you needed two different conditions and you can create this one when you want to have denitrification because you need some organics because the problem here is most of the organics is removed on this one and when you come to the denitrification you don't have sufficient amount of organics okay and that is what we found so the way we have developed we have this the pva gel compartment in that compartment we need to add organics for denatification take place so similarly you need to look that two reactors approach could be an interesting one okay whether to go for a simultaneous nitrogen and denitrification or we could have like you say you need to have two different sources so we need to add a source of organics okay to create that ratio of cod2 nitrogen ratio it's very important and people are working on this the intermittent aviation step feeding and periodic back washing these are the things we need to look into that as i told you we don't want the biofilm to grow too much so sometimes we need to remove that by frame how do you remove it some type of back washing might be interesting and there are researchers working on this one high breed mabr system okay so what we're doing is they have an anaerobic zone depending on the feed condition okay because you need to get the correct c to n ratio okay and this compartment may be our problem so you might be good to have anaerobic zone first okay to reduce the amount of cod as much as possible and the nitrogen balance comes with it then you can have the last part okay a fine bubble variation okay well there are people are working on different configurations one of the interesting work okay we are working at the moment is is looking at the membrane configuration so for example how bioflame is done okay one thing is is the micro biofilm could be kept in one strong stage or you could sorry not by frame the fiber could be kept in there one straight or you could make this the membrane fiber bit loose because when you keep like this okay the membrane is not relaxed okay so what happens is here it is very interesting concept when you want to filter water okay like a water treatment and etc please keep in mind many of the conventional honor fiber membranes are designed for filtration application so that means you have the water to be filtered okay so but they are not designed for a biofilm to grow okay if you want the biofilm to grow in a membrane if you look at it here if you like a big bundle the inner part of the fibers there is no possibility of biofilm to grow so what we need to do is we need to redesign the membrane and we redesign it in such a way there are published papers you can see custodial et cetera working on these there are people who researchers are working on this how you redesign so that the biofilm is grown hundred percent within the whole fiber body it's very important okay we don't want the biofuel to go only on outer surface okay outside but we need to do it so we are working on this i think there are a lot of research goes on this and this might be an interesting thing let me come to the sort of my last part of my presentation the cutting edge of mabr application could be looked into two things one is a bioreactor characteristic second one is operating condition in a bioreactor characteristic you need to look at membrane permeability specific surface area the membrane surface chemistry okay say for example traditionally membrane produces produced membrane so that the biofilm will not grow on the surface okay but here we want exactly opposite we want the biofilm to grow on the surface so that means the chemistry need to be changed okay and we need to work with organic chemist how do you create membranes in which biofilm can grow whereas 99 percent of the industry is producing membrane in which membrane biofilm will not grow different condition okay we need to look at it how do you do this aviation regimen etcetera now the second part is the first part is bioreactor characteristic the second part is we need to look at the operating condition how do you operate your reactor i think if you work on a nitrification and denitrification in a biological process the cod to the night regeneration is very important and many situation it doesn't meet the optimum condition so you need to consider how do you create that optimal condition between five to ten okay if your feed water is not good if it doesn't you need to develop a strategy to bring that range to our best notification d notification hydraulic retention time we need to bring down okay all the industrial applications works around 10 hours and our dream is to bring less than three to somewhere between six to three hours it's a challenge and that is what will take us further okay intramembrane pressures temperature ph as i told you okay cross flow velocity at what velocity you do that how do you control bioflame and etcetera this all looks into this hydrodynamic channeling i told you you have a bundle the whole biomass is on the outside there's inner part not much so there is a hydro dynamic channeling takes place by frame thickness bio flame micro uh morphology and the density and we need to work very strongly with biofilm and biological people and how whether it's what type of biofilm is growing how do you control and etcetera it's very important we cannot just look this research just a chemical or environmental engineering we need to work very strongly and very closely with microbiologists performance can be looked at vod cod removal suspended solids nitrogen removal sludge yield okay it's quite interesting the sludge yield is simply much okay quite attractive and also we need to look at aeration efficiency as i said we are going to have this cross flow mold so we also have to make sure the system is efficient enough okay the exhaust air which comes out okay what do you do with that okay and we can think about them etc we'll come back to the next one let me finish off my presentation with this last slide uh my i've been working on this field for last five years uh let me summarize on my understanding what are the research gaps in this domain where young researchers like you might be able to work difficulty in maintaining an optimum biofilm thickness as i said we are simultaneously two process taking place in a single reaction okay if you want to do that you need to control the biofuel thickness it's a challenge and please keep in your mind you're talking not on a flat shape okay like for example in trickling filter it's a flat shape with only one surface but here you hold a fiber it's a bundle what happens inside the core and what happens outside is different time requirement for initial biofilm formation exactly a trickling filter and an activated process activation process you can start maybe you can start like this but m a br you needs sufficient time the biofilm has to grow it can take between anywhere between two to four weeks okay so we need to think about that how do we accelerate in a real applications sensitivitiness of the bioframe to the changes in ph and temperature and salinity it's very important possibility and membrane defects such as whether what happens okay if your pre-treatment failure whether make the membranes as a bundle as we see in a conventional membrane bioreactor process okay if your pre-treatment is not good especially if your waste water contains air and if the pre-treatment doesn't take the air outside the and the air will go inside the bundle and make the bundle into a like a tangle okay so that it cannot move and that creates a lot of operation problem same thing can happen poor understanding mechanism see there's not much work has been done from a laboratory pilot scan and how do you move the industry that is something we need to work with might be very challenging integration of mabr with other advanced oxidation technologies improvement in nitrification and denatification process within the reactor still we were able to achieve only around 60 to 70 percent of the total nitrogen removal but our aim is to to 98 how do you achieve that that's important significant reduction in hydraulic reduction time as i said if you wanted to achieve an iron nitrogen removal one of the ways is we can increase hydraulic retention time and then it becomes not attractive so we need to look at it how we can couple or modify this whole process the hydraulic reduction times can be reduced and total nitrogen can be uh sorry hydraulic retention time is reduced with the total nitrogen reduction is removal is increased let me finish my presentation it's almost an hour it may be a believe me or not it's a game changer with respect to energy footprint of biological treatment process any of the biological treatment process will work and if there is an energy consumption issues which is a problem in an accurate size process any of the aerobic process please understand this is in competition with aerobic process it's not in competition with anaerobic process with dr howard going to present on friday okay so this is if you're talking about aerobic process if you're worried about your energy footprint or energy consumption mabr will be a really a game changer okay very attractive and there's a lot of scope for working on this with this note thank you very much let's have next few minutes for discussion questions thank you okay uh thank you vishu so i will will i will uh probably uh the already some question right uh beta okay please be there okay can i start with a checklist in that way yes there is some questions here so many questions actually okay we will uh okay read the questions okay i'm saying that i have uh this is okay is it may be a system applied for industry or still study research phase okay ah yeah i can i can can i answer the question one by one ah yes yes please yes please if maybe a system is applied in industry or still in study research mabr is to large extent in a research but it moved from laboratory to pilot scale okay but there are few uh there is only one published paper on a large-scale mabr in china for a pharmaceutical industry uh it's it's a very big plot but there are a lot of how do i say holes in the indus scale application i think there is lot more research need to be done i don't i will not say it is industry scale application fully but it's moving it has moved to certain extents okay is that okay the first answer yes okay thank you okay how to make sure the separation of microbial layer in a bioframe is separate clearly if there's any probability to mix them in one layer um i think the question comes is that what type of microorganism presence aerobic or anoxic okay depends on the amount of oxygen which can diffuse through okay so at the closest to the membrane surface you have an aerobic system and as the oxygen diffuses through so you cannot separate it out if the separation takes place naturally by the presence of oxygen okay okay so it's naturally separately speculative it's not separately it is one biofilm the inner part for what thickness it depends on the oxygen diffuses through okay so if you look at a fiber the fiber is like this long fiber okay on the top you'll have more oxygen at the bottom you'll have less oxygen as it passes through okay the biofilm on the top of the fiber and the biofilm at the bottom of the fiber will be different because the amount of oxygen diffuses is different so that's the that's an important part okay how about mass transfer resistant of oxygen water membrane layer micro are there any civilian this is a very important issue these are the ones the chemical engineers are working on this okay and in fact we also doing a lot of work on i did not present it here we also work on the resistance oxygen what we call oxygen transfer rate how to improve the oxygen transparent and that's why i said what type of hydraulic circulation we keep within the reactor to improve the oxygen transfer rate okay and also i told you how you design your membrane do you design as a bundle or you design a bit loose and we use this word relaxation rate that we need to be study honestly that's one of the part of the research we are working number three number four do we need a mixing system inside aviation time yes that's as i said you need to look at it how is the oxygen transfer rate so sometimes it's good to have hydraulic mixing okay for two reasons to improve the oxygen transfer rate second thing we don't want the membrane biofilm to grow too thick okay and we want the biofilm to remove just remember trickling filter if the biofilm grows the water cannot penetrate percolate so you have flooding of tickling filters similarly we don't want biofilm to grow too much so we need to mix it and continuously remove the wireframe so you need to have mixing condition depending on your reactor okay so we don't need another of mechanical mixer like uh architecture yes you saw the reactor i we showed you now an aborted scale we use that one depending on oxygen transformation okay can i go to the next one from irvine yes yes is there is a company which already has a cas treatment plant wants to convert it do do they only need to switch activate such process too yeah see please understand if you are using membrane bioreactor you don't need a secondary sedimentation okay but if you're using membrane aerated by affirmative you need a secondary clarifier okay please understand the biomass has to be removed so secondary clarifier is necessary okay as i said it's become very attractive when you're focusing on nitrification and denitrification okay okay if your focus is on nitrogen removal yes it becomes so you can easily convert a conventional activity forces into an mabr using the secondary sedimentation okay is it still possible to simply use air rather than a pure oxygen please understand that industrial scale we will never use pure oxygen okay because it
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